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cause of high alkalinity of boiler water

What is boiler water PH? And why so maintained? - Quora

Controlling pH. Alkalinic water is more prone to scaling.Alkalinity is a measure of the bicarbonate (HCO3), carbonate (CO3) and hydroxyl (OH) ions in the water. PH control is related to Acidic Corrosion- Low makeup or feed water pH can cause serious acid attack on metal surfaces in the boiler system.

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Boiler Water Conductivity Measurement Fundamentals

Boiler Water Conductivity Measurement Fundamentals. There are several causes for whilst foaming; high levels of suspended solids, high alkalinity or contamination by oils and fats but, the most common cause of carryover (provided these other factors are properly controlled) is a high Total Dissolved Solids (TDS) level.

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Troubleshooting: Condensate Contamination

Boiler carryover is just as likely to have a mechanical cause as it is a chemical cause. Mechanical carryover causes include: x Excessive movement of water in the steam drum. x Spray or mist carryover from fine water droplets. This usually occurs when separation devices are missing or damaged.

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alkalinity – Water Technology Report

Jul 26, 2016 · Boiler Alkalinity. Regulating the alkalinity of the boiler water (carbonate and hydroxide) is an important consideration because excessive concentrations can lead to the attack of the porcelain insulators used as lead-through bushings to bring the electrical power into the boiler.

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Properly Treat Boiler Water for Efficient, Long -Term Operation

Boiler feedwater also contains dissolved gases, such as carbon dioxide and oxygen, that react in a boiler and lead to corrosion of the boiler internals and the piping system. If these gases are not extracted from the water supply before entering the boiler, the corrosion will eventually eat through boiler tubes and cause leaks and equipment failure.

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High-Pressure Steam Cycle and Boiler Water Treatment

Boiler Water-Side Internals • Deposit accumulations – Caustic cracking or caustic corrosion • Excess hydroxide alkalinity – Metal oxides such as iron and copper • Copper from heat exchangers transported to the boiler due to low pH and/or ammonia • Copper on boiler tubes cause overheating and galvanic corrosion

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ALKALINITY CONTROL - Guardian CSC

boiler water alkalinities rise above the recommended maximum, reduce the feed of alkali bearing materials or reduce the total alkalinity of the treated water if a softener is used. In an emergency, increase the blow down rate if necessary to bring boiler water alkalinity under control. Sodium hydroxide is the preferred approach, as the break down components does not form carbon dioxide.

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Boiler Carryover – Cause, Effect and Prevention

Aug 14, 2017 · In low/medium pressure boilers (<100 bar) entrained boiler water is the most common cause of steam contamination. Both mechanical factors such as boiler design, high water levels, load characteristics and chemical factors such as high solids concentration, excessive alkalinity, presence of contaminants contribute to the creation of carryover.

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What Causes High Alkalinity in Water? | Healthfully

Jul 27, 2017 · Causes of Alkalinity. Alkalinity in a solution means the solution is capable of buffering acidic solutions with higher concentrations of hydrogen ions. Alkalinity in water comes from a high concentration of carbon-based mineral molecules suspended in the solution. Water with high alkalinity is said to be "hard.".

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Case Study: Depressed Feedwater pH - Veolia Water

Carbonate-based alkalinity in the boiler breaks down under the high heat and pressure and is released with the steam as carbon dioxide. Carbon dioxide dissolves into the condensed steam to form carbonic acid which lowers the pH of the condensate. RO permeate is stored in a permeate storage tank with the water constantly

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What are the consequences of low alkalinity in boiler water

Oct 13, 2009 · To control the alkalinity of boiler water which is directly related to pH control. Too alkaline will cause stainless steel to brittle while too low alkalinity will cause corrossion.

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Steam Boiler Flooding & Surging Causes & Repairs

It is not likely that simply removing, cleaning, and replacing the sight glass would itself cause abnormally high (or low) water levels in a steam boiler. High water readings in the sight glass of a steam boiler, also referred to by the pros as a flooded steam boiler are most-likely caused by one of the following, of which surging is perhaps the most common problem.

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pH Treatment | CleanBoiler.org - Boiler Consortium

Its caustic concentration can be as high as 10,000-100,000 ppm. Careful control of boiler water chemistry can prevent caustic gouging. If the “free hydroxide alkalinity” is set too high or uncontrolled, then caustic gouging may result. Prevention of porous deposit formation (such as iron oxide) eliminates a place for caustic gouging to occur.

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The Effects of Carryover in Steam Boiler Systems

Aug 14, 2018 · The alkalinity in boiler water can react with these contaminants to produce a crude soap that causes foaming and carryover. Selective vaporous carryover occurs due to the solvent properties of steam. At high pressures, steam actually dissolves a portion of the mineral salts in boiler water.

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Alkalinity Builders | Boiler Water Treatment Chemicals

Acid Attack Acid attack in a boiler can be caused by low make-up feed water pH which attack the metal surfaces within the boiler system either causing a generalised thinning or localised corrosion of high-stress areas.

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What is the reason for keeping a boiler feed water pH lower

Aug 06, 2018 · About 100 cc of water can dissolve up to 30grams of ammonia forming concentrated Ammonia hydroxide whose presence gives the higher alkalinity which are usually noticed in Boiler steam drums. Remember the dryness fraction of steam before they go through super heaters. V= Vx + Vg.

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High-Purity Boiler Water pH Measurement

The correct pH measurement is essential to water treatment: pH too high or too low can lead to boiler or steam turbine scaling and corrosion, system failures, and downtime, as well as the costly

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Alkalinity and phosphate - tpub.com

The boiler must never be surface blown if this action will cause boiler water limits to go below the minimum requirements for alkalinity and phosphate, regardless of the chloride level. A 10 percent blowdown will cause the phosphate, alkalinity, and chloride levels to drop by 10 per-cent.

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66- Internal Feedwater Treatment Flashcards | Quizlet

Foaming of water in the boiler. a) is due to a high concentration of dissolved gases b) can be controlled by adding sodium phosphate c) can be controlled by adding more neutralizing amines. d) can be controlled by adding sulphur to the feedwater. e) can be controlled by the bottom and continuous blow downs.

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What are the causes of high alkalinity in boiler water?

1.high alkalinity causes scale formation on the walls of the heating surface so it reduces the heat transfer from the surface to water. 2.the ph value is very difficult to be adjusted 3.eye and skin irritation 4.it affects the feed water treatment by poor filtration of water

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What causes low total alkalinity - Answers

Total alkalinity (TA) is the amount of pH buffering capability of your water. Low TA allows for pH to change rapidly. High TA on the other hand makes changing pH difficult.

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Boiler water chemistry - Properties of feed water explored

The conventional boiler water test finds only the presence of OH and half of CO3. Standard value of P alkalinity in Boiler Water is between 50-300mg CaCO3/l. Effects. Higher value of P alkalinity leads to scale formation and overheating of the inside of the boiler causing internal damage. 6. Chloride ion. It causes generation of scale formation.

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Boiler Alkalinity - Boiler Chemical Treatment Products

Boiler Alkalinity Boiler Alkalinity chemicals are used to increase the boiler water pH within the boiler water. The mild steel boiler tubes prefer higher pH waters. Increasing the boiler pH may reduce corrosion rates, allow the polymer to activate, and minimize silica scaling. ChemWorld stocks 25% and 50% of alkalinity solutions.

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Water Handbook - Preboiler & Industrial Boiler Corrosion

If a boiler water possesses embrittling characteristics, steps must be taken to prevent attack of the boiler metal. Sodium nitrate is a standard treatment for inhibiting embrittlement in lower-pressure boiler systems. The inhibition of embrittlement requires a definite ratio of nitrate to the caustic alkalinity present in the boiler water.

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Boiler Water Conductivity Measurement Fundamentals

A relatively high frequency (for example 1 000 Hz) is necessary to avoid polarization at the high conductivities of boiler water. Whilst the boiler water conductivity is converted to a resistance through the probe, it cannot be measured using a simple dc resistance meter.

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alkalinity – Water Technology Report

Jul 26, 2016 · Regulating the alkalinity of the boiler water (carbonate and hydroxide) is an important consideration because excessive concentrations can lead to the attack of the porcelain insulators used as lead-through bushings to bring the electrical power into the boiler.

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Testing Alkalinity In Boiler Water - Taylor

Testing Alkalinity In Boiler Water. Alkalinity is a key control parameter for boilers (outside of the prescribed operating range, it can lead to corrosion, caustic metal embrittlement, and carryover) and cooling water systems (where it has a significant effect on chemical treatments for scale and corrosion inhibition).

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Foaming and priming in boilers - Lenntech

Priming is common cause of high levels of boiler water carryover. These conditions often lead to super heater tube failures as well. Priming is related to the viscosity of the water and its tendency to foam. These properties are governed by alkalinity, the presence of certain organic substances and by total salinity or TDS. The degree of priming also depends on the design of the boiler and its steaming rate.

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Total Alkalinity vs. pH, and Their Roles in Water Chemistry

Oct 05, 2016 · Low pH can cause damage to pool liners and etching of plaster; corrosion of metal components in and around the pool; skin and eye damage, as well as general patron discomfort; and a reduction of total alkalinity. On the other hand, high pH water can cause scale formation; metal stains; cloudy water; poor efficiency of chlorine, and also can cause skin and eye irritation.

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What Causes High Alkalinity in Swimming Pools? | Garden Guides

High alkalinity is easily solved by adding sodium bisulfate to your swimming pool, which is often marketed as pH and alkalinity increaser or pH-up. The chemical to lower both alkalinity and pH is one and the same. To accurately lower the alkalinity to the right levels, you must test the water.

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What is the effect of high alkaline water to a boiler?

What is the effect of high alkaline water to a boiler?.. Answer / shaunak kulkarni Fast corrosion of boiler is caused by highly alkaline water,during steam generation,especially in those boilers which produce high pressure steam.

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THE BASICS OF BOILER WATER CHEMISTRY

• The #1 cause of boiler tube failure is Oxygen Corrosion • Small amount of boiler water drawn off near surface Alkalinity enters the boiler in the make

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Properly Treat Boiler Water for Efficient, Long -Term Operation

Boiler feedwater also contains dissolved gases, such as carbon dioxide and oxygen, that react in a boiler and lead to corrosion of the boiler internals and the piping system. If these gases are not extracted from the water supply before entering the boiler, the corrosion will eventually eat through boiler tubes and cause leaks and equipment

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boiler water high alkalinity.what causes it? | Yahoo Answers

Jun 28, 2009 · boiler water high alkalinity.what causes it? 1 Answer Generally its due to corrosion in the copper pipes.

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The Importance of Boiler Water and Steam Chemistry

Common causes of foaming are excessive solids or alkalinity, and the presence of organic matter such as oil. Keeping dissolved solids below the concentration that causes foaming requires continuous or periodic blowdown of the boiler. High boiler water alkalinity increases the potential for foaming, particularly in the presence of suspended matter.

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Basics of Marine Engineering: BOILER WATER

Nov 29, 2012 · Eliminate the total hardness of the boiler water; Maintain correct pH and alkalinity values in feed water and boiler water; Prevent Corrosion, especially that caused by O2; Prevent formation of scale, by conditioning of sludge; Avoid Foaming; Now what's Foaming?

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Alkaline Water: Benefits, Side Effects, and Dangers

May 30, 2019 · The “alkaline” in alkaline water refers to its pH level. The pH level is a number that measures how acidic or alkaline a substance is on a scale of 0 to 14. For example, something with a pH of 1 would be very acidic, and something with a pH of 13 would be very alkaline. Alkaline water has a higher pH level than regular drinking water.

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Dealkalization | Alkalinity - Process Water | Water Purification

High alkalinity may require that a boiler operate at shorter cycles, wasting energy and chemicals due to high blowdown. A cycle is the measure of how concentrated water has become inside a boiler. Concentration levels may be measured by dividing the conductivity of the boiler blowdown by the conductivity of the feedwater.

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Should You Have a Dealkalizer as Part of Your Boiler Water

Hydroxyl alkalinity (OH-) that comes from soda ash or caustic addition is vital to ensuring the proper chemical mechanics are in place for scale inhibition and corrosion prevention; however, naturally occurring alkalinity in the form of carbonate (CO3-) and bicarbonate ions (HCO3-) found in most water makeup sources can cause the following two issues:

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What problems come from high Total Alkalinity | Trouble Free Pool

High TA can cause a few different problems. 1) pH keeps going up. 2) Cloudy water. 3) Burning eyes and itchy skin. I have also heard it can cause reduced chlorine efficiency though not sure on that one.

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